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Chipotle powder has a unique flavor that can be a bit challenging to replicate. It has some heat, as most chili-based spices and seasonings do, but it also has some smoky flavor notes and a bit of earthiness, per Pepper Scale. Ancho chili powder is similar in color to chipotle powder, and is a staple seasoning for Mexican cuisine. On the other hand, if you find chipotle powder to be a bit on the spicy side, this substitute might even make your recipe more to your liking. Since ancho chili powder is a bit more mild than chipotle powder, you can be a bit more generous in your substitution — for every tablespoon of chipotle powder a recipe calls for, you can swap in about a tablespoon and a half of ancho chili powder, and then adjust according to taste. If you’re all about spicy food, cayenne just might be a worthy substitute for chipotle powder in your recipe.